ANALYSIS OF THE CHARACTERISTICS AND PERFORMANCE OF POLYETHERSULFONE/POLYCAPROLACTONE MEMBRANES FABRICATED USING THE ELECTRIC FIELD METHOD FOR WATER FILTRATION APPLICATIONS
Abstract
This study developed polyethersulfone/polycaprolactone (PES/PCL) composite membranes using the electric field-assisted non-solvent induced phase separation (NIPS) method for water filtration applications. The effect of PES/PCL composition and electric field application on membrane morphology, hydrophilicity, mechanical properties, chemical stability, permeability, and filtration performance was systematically investigated. Four membrane samples were prepared, consisting of MM0 (100% PES, conventional NIPS), MM1 (70% PES + 30% PCL), MM2 (80% PES + 20% PCL), and MM3 (90% PES + 10% PCL), with the latter three fabricated under a 15 kV electric field. SEM and AFM analyses revealed that MM1 exhibited the most homogeneous interconnected finger-like pore structure, the largest pore size, and the smoothest surface morphology. FTIR and XRD analyses confirmed good intermolecular interactions between PES and PCL and improved semi-crystalline structure in MM1. Hydrophilicity tests showed that MM1 achieved the highest porosity (89.27%), water uptake (145.15%), and the lowest tortuosity (1.12). Mechanical testing demonstrated superior tensile strength (21.07 MPa) and structural stability for MM1. In addition, MM1 exhibited the highest clean water permeability of 114.3 L·m⁻²·h⁻¹·bar⁻¹ and the best rejection efficiency for electrical conductivity, total dissolved solids, and turbidity. Overall, the combination of PES/PCL blending and electric field-assisted NIPS effectively enhanced membrane performance for advanced water filtration applications.
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References
- 1. Diepenbroek E, Mehta S, Borneman Z, Hempenius MA, Kooij ES, Nijmeijer K, et al. Advances in Membrane Separation for Biomaterial Dewatering. Langmuir. 2024;40(9):4545–66. DOI: 10.1021/acs.langmuir.3c03439
- 2. Cheng X, Bae J. Recent Advancements in Fabrication, Separation, and Purification of Hierarchically Porous Polymer Membranes and Their Applications in Next-Generation Electrochemical Energy Storage Devices. Polymers (Basel). 2024;16(23):3269. DOI: 10.3390/polym16233269
- 3. Sun H-L, Wang L-C, Zhou X-Y, Wei Y-M, Liu M. A dual VIPS-RTIPS phase inversion technique for fabricating high-performance polyethersulfone (PES) ultrafiltration membranes. Chem Eng Sci. 2026;321:122821. DOI: 10.1016/j.ces.2025.122821
- 4. Firdaus A, Mataram A, Dani R, Satya Putra Gantada M, Bizzy I, Fauzi Ismail A. Physicochemical Properties and Water Filtration Performance Of Electric Field Fabricated Polyvinylidene Fluoride Membranes. Science and Technology Indonesia. 2026;11(3). DOI: 10.26554/sti.2026.11.3
- 5. Hussein S, Saed UA, Al-Furaiji M. Characterization and performance of PSF ultrafiltration membranes embedded with MWCNTs for oily wastewater treatment. Desalination Water Treat. 2025;323:101413. DOI: 10.1016/j.dwt.2025.101413
- 6. Sriyanti I, Almafie MR, Dani R, Marlina L, Mulyani LN, Idjan RSA, et al. Optimization of PVP/PCL nanofiber diameter using coaxial electrospinning: response surface methodology and physicochemical characterization. S Afr J Chem Eng. 2026;55:298–315. DOI: 10.1016/j.sajce.2025.11.023
- 7. Yang X, Bai R, Cao X, Song C, Xu D. Modification of polyacrylonitrile (PAN) membrane with anchored long and short anionic chains for highly effective anti-fouling performance in oil/water separation. Sep Purif Technol. 2023;316:123769. DOI: 10.1016/j.seppur.2023.123769
- 8. Gryta M, Woźniak P. Application of polypropylene microfiltration membranes for separation of wastewater from car wash. Sep Purif Technol. 2024;331:125707. DOI: 10.1016/j.seppur.2023.125707
- 9. Ghodke YA, Mayilswamy N, Kandasubramanian B. Polyamide (PA)- and Polyimide (PI)-based membranes for desalination application. Polymer Bulletin. 2023;80(10):10661–95. DOI: 10.1007/s00289-022-04559-7
- 10. Mataram A, Firdaus A, Yanis M, Dani R, Nasir S, Ismail AF, et al. Synthesis of polyethersulfone/titanium dioxide membranes: analysis of morphology, mechanical properties, and water filtration performance. Eastern-European Journal of Enterprise Technologies. 2024;6(6 (132)):16–25. DOI: 10.15587/1729-4061.2024.316523
- 11. Zheng S, Yang S, Ouyang Z, Zhang Y. Robust and highly hydrophilic ultrafiltration membrane with multi-branched cellulose nanocrystals for permeability-selectivity anti-trade-off property. Appl Surf Sci. 2023;614:156157. DOI: 10.1016/j.apsusc.2022.156157
- 12. Mizan MMH, Rastgar M, Sultana H, Karami P, Sadrzadeh M. Green polycaprolactone/sulfonated kraft lignin phase inversion membrane for dye/salt separation. J Memb Sci. 2024;702:122806. DOI: 10.1016/j.memsci.2024.122806
- 13. Tasci RO, Kaya MA, Celebi M. Hydrophilicity and flux properties improvement of high performance polysulfone membranes via sulfonation and blending with Poly(lactic acid). High Perform Polym. 2022;34(10):1115–30. DOI: 10.1177/09540083221110031
- 14. Shen Y, Badireddy AR. A Critical Review on Electric Field-Assisted Membrane Processes: Implications for Fouling Control, Water Recovery, and Future Prospects. Membranes (Basel). 2021;11(11):820. DOI: 10.3390/membranes11110820
- 15. Sun F, Yang J, Shen Q, Li M, Du H, Xing DY. Conductive polyethersulfone membrane facilely prepared by simultaneous phase inversion method for enhanced anti-fouling and separation under low driven-pressure. J Environ Manage. 2021;297:113363. DOI: 10.1016/j.jenvman.2021.113363
- 16. Firdaus A, Nasir S, Dani R, Prasatya IN, Ismail AF, Othman MHD, et al. Synthesis of polyethersulfone membranes with the addition of silver nitrate for water filter applications. EUREKA: Physics and Engineering. 2024;(1):121–31. DOI: 10.21303/2461-4262.2025.003394
- 17. Firdaus A, Dani R, Gantada MSP, Ismail AF, Nukman N, Bizzy I, et al. Identifying the features of mechanical and physicochemical characteristics of polyethersulfone membranes using electric field method for water filtration applications. Eastern-European Journal of Enterprise Technologies. 2025;6(6 (138)):14–27. DOI: 10.15587/1729-4061.2025.339703
- 18. Alam MdN-E, Deowan SA, Efty SS, Chowdhury F, Haque Milon A, Nurnabi M. Fabrication and performance evaluation of polyethersulfone membranes with varying compositions of polyvinylpyrrolidone and polyethylene glycol for textile wastewater treatment using MBR. Heliyon. 2024;10(16):e36215. DOI: 10.1016/j.heliyon.2024.e36215
- 19. Ramkumar N, Monash P. Fabrication of PES membranes using pure and mixed aprotic solvents (DMSO-DMAc) for enhanced membrane distillation. J Environ Chem Eng. 2025;13(6):119571. DOI: 10.1016/j.jece.2025.119571
- 20. Sriyanti I, Almafie MR, Nuha Ap Idjan MK, Dani R, Solihah I, Syafri E, et al. Electrospun nanofiber membrane of Piper beetle loaded PVDF/PAN for medical mask applications: psychochemical characteristics, antibacterial and air filter test. Advanced Membranes. 2025;5:100149. DOI: 10.1016/j.advmem.2025.100149
- 21. Sriyanti I, Almafie MR, Dani R, Marlina L, Mulyani LN, Idjan RSA, et al. Optimization of PVP/PCL nanofiber diameter using coaxial electrospinning: response surface methodology and physicochemical characterization. S Afr J Chem Eng. 2026;55:298–315. DOI: 10.1016/j.sajce.2025.11.023
- 22. Almafie MR, Fudholi A, Dani R, Idjan MKNA, Royani I, Sriyanti I. Effects of electrospinning parameters on polycaprolactone membrane diameter: An investigation utilizing central composite design and characterization. Results in Engineering. 2025;25:104002. DOI: 10.1016/j.rineng.2025.104002
- 23. Dani R, Ismet, Marlina L, Alisya R, Aldi MAK, Ludiansyah A, et al. Synthesis of Activated Carbon from Coconut Shell and Recycled Styrofoam Nanofiber for Water Filtration. Makara J Sci. 2024;28(4). DOI: 10.7454/mss.v28i4.2284
- 24. Dani R, Almafie MR, Mataram A, Lamura MDP, Akhsan H, Marlina L, et al. Preparation of Polyacrylonitrile-Polyethersulfone Nanofibers Loaded with Reduced Graphene Oxide from Palm Kernel Shell forWastewater Filtration. Science and Technology Indonesia. 2026;11(2):457–80. DOI: 10.26554/sti.2026.11.2.457-480
- 25. Geng X, Wang J, Ding Y, Zhang W, Wang Y, Liu F. Poly(vinyl alcohol)/polydopamine hybrid nanofiltration membrane fabricated through aqueous electrospraying with excellent antifouling and chlorine resistance. J Memb Sci. 2021;632:119385. DOI: 10.1016/j.memsci.2021.119385
- 26. Alkawareek MY, Akkelah BM, Mansour SM, Amro HM, Abulateefeh SR, Alkilany AM. Simple Experiment to Determine Surfactant Critical Micelle Concentrations Using Contact-Angle Measurements. J Chem Educ. 2018;95(12):2227–32. DOI: 10.1021/acs.jchemed.8b00276
- 27. Li K, Peng H. Nanostructured Membranes with Interconnected Pores Via a Combination of Phase Inversion and Solvent Crystallisation Approach. 2023.
- 28. Prasad NS, Gayatri NL, Sandhya BN, Kalyani S, Bhargava SK, Sridhar S. Hydrophilized Ultrafiltration Membranes Synthesized from Acrylic Acid Grafted Polyethersulfone for Downstream Processing of Therapeutic Insulin and Cobalamin. Appl Biochem Biotechnol. 2022;194(8):3400–18. DOI: 10.1007/s12010-022-03822-x
- 29. Yang S, Ren M, Li D, Zhang Y, Zhang H. Enhancing PES ultrafiltration membranes with amphiphilic copolymer for improved dye and salt removal in textile wastewater. J Environ Chem Eng. 2026;14(3):122290. DOI: 10.1016/j.jece.2026.122290
- 30. Talukder ME, Pervez MdN, Song H, Buonerba A, Stylios GK, Naddeo V, et al. Eco-friendly synthesis of porous and charged polyethersulfone membrane for improved protein separation efficiency. Results in Engineering. 2025;25:104422. DOI: 10.1016/j.rineng.2025.104422
- 31. Qin Z, He B, Pan X, Zhang Z, Zhang L, Li X. Tuning phase inversion kinetics and membrane structure via sulfonation degree in PES/SPSf blending system for high-performance loose nanofiltration. J Memb Sci. 2026;743:125177. DOI: 10.1016/j.memsci.2026.125177
- 32. Mizan MMH, Rastgar M, Sultana H, Karami P, Sadrzadeh M. Green polycaprolactone/sulfonated kraft lignin phase inversion membrane for dye/salt separation. J Memb Sci. 2024;702:122806. DOI: 10.1016/j.memsci.2024.122806
- 33. Lau H, Lau S, Soh L, Hong S, Gok X, Yi S, et al. State-of-the-Art Organic- and Inorganic-Based Hollow Fiber Membranes in Liquid and Gas Applications: Looking Back and Beyond. Membranes (Basel). 2022;12(5):539. DOI: 10.3390/membranes12050539
- 34. Basko A, Lebedeva T, Yurov M, Ilyasova A, Elyashevich G, Lavrentyev V, et al. Mechanism of PVDF Membrane Formation by NIPS Revisited: Effect of Precipitation Bath Nature and Polymer–Solvent Affinity. Polymers (Basel). 2023;15(21):4307. DOI: 10.3390/polym15214307
- 35. Lin S, He S, Sarwar S, Milescu RA, McElroy CR, Dimartino S, et al. Spray coating polymer substrates from a green solvent to enhance desalination performances of thin film composites. J Mater Chem A Mater. 2023;11(2):891–900. DOI: 10.1039/D2TA07200A
- 36. Shen Y, Badireddy AR. A Critical Review on Electric Field-Assisted Membrane Processes: Implications for Fouling Control, Water Recovery, and Future Prospects. Membranes (Basel). 2021;11(11):820. DOI: 10.3390/membranes11110820
- 37. Lim QF, Yap RCC, Teng CP, Yeo JCC, ... Electrospray-on-electrospun breathable, biodegradable, and robust nanofibrous membranes with photocatalytic bactericidal activity. ACS Applied Nano …. ACS Publications; 2023; DOI: 10.1021/acsanm.2c04776
- 38. Bohr SJ, Wang F, Metze M, Vukušić JL, Sapalidis A, Ulbricht M, et al. State-of-the-art review of porous polymer membrane formation characterization—How numerical and experimental approaches dovetail to drive innovation. Frontiers in Sustainability. 2023;4. DOI: 10.3389/frsus.2023.1093911
- 39. Huang Y-H, Seenuvasan S, Wang M-J, Chung T-S. Effects of polyvinylidene difluoride (PVDF) molecular weight on hydrophobic membranes prepared by the plasma assisted nonsolvent induced phase separation (PANIPS) method. Chemical Engineering Journal. 2025;505:159147. DOI: 10.1016/j.cej.2024.159147
- 40. Wang Y, Li Y, Zhang W, Lin L. Fabrication and functionalisation of poly(ε-caprolactone)-based materials for water treatment: A comprehensive review. J Environ Chem Eng. 2026;14(1):120966. DOI: 10.1016/j.jece.2025.120966
- 41. Hosseinzadeh F, Sarpoolaky H. Advances in tight ultrafiltration membranes: Material development, performance enhancement, and sustainable applications. Journal of Hazardous Materials Advances. 2025;19:100813. DOI: 10.1016/j.hazadv.2025.100813
- 42. Bhagyaraj S, Parangusan H, Madhusudanan SP, Elshazly TM, Ponnamma D. Poly(vinylidenefluoride) based nanocomposites-structural and functional materials for the future. Adv Compos Hybrid Mater. 2026;9(1):30. DOI: 10.1007/s42114-025-01524-6
- 43. Chong HY, Muhammad SAH, Norazmi SN, Chang ZH, Teoh YH. A Review on Membrane Fabrication: Structure, Properties and Performance Relationship. Journal of Applied Membrane Science & Technology. 2025;29(1):73–97. DOI: 10.11113/jamst.v29n1.311
- 44. Alkandari SH, Castro-Dominguez B. Advanced and sustainable manufacturing methods of polymer-based membranes for gas separation: a review. Frontiers in Membrane Science and Technology. 2024;3. DOI: 10.3389/frmst.2024.1390599
- 45. Roy D, Mandal S, Chandrakar K, Dwivedi M. Controlling Porosity and Multifunctionality in Electrospun Polymeric Fibers by Nanoscale Phase Separations: Flory–Huggins Interaction Parameters Revisited. Macromol Chem Phys. 2025;226(13). DOI: 10.1002/macp.202500046
- 46. Wang Y, Li Y, Zhang W, Lin L. Fabrication and functionalisation of poly(ε-caprolactone)-based materials for water treatment: A comprehensive review. J Environ Chem Eng. 2026;14(1):120966. DOI: 10.1016/j.jece.2025.120966
- 47. Nain A, Sangili A, Hu S-R, Chen C-H, Chen Y-L, Chang H-T. Recent progress in nanomaterial-functionalized membranes for removal of pollutants. iScience. 2022;25(7):104616. DOI: 10.1016/j.isci.2022.104616
- 48. Yousefian-Arani M, Sharif A, Karimi M. Thermodynamic analysis of polymeric membrane formation by non-solvent induced phase separation in the presence of different nanoparticles. J Mol Liq. 2022;362:119732. DOI: 10.1016/j.molliq.2022.119732
- 49. Bergamasco S, Fiaschini N, Hein LA, Brecciaroli M, Vitali R, Romagnoli M, et al. Electrospun PCL Filtration Membranes Enhanced with an Electrosprayed Lignin Coating to Control Wettability and Anti-Bacterial Properties. Polymers (Basel). 2024;16(5):674. DOI: 10.3390/polym16050674
- 50. Li H, Che K, Jiang P, Yin F, Li Z, Wang X, et al. High-Performance Membranes Based on Spherical-Beaded Nanofibers and Nanoarchitectured Networks for Water-in-Oil Emulsion Separation. Nano Lett. 2024; DOI: 10.1021/acs.nanolett.4c02954
- 51. Nasution MS, Mataram A, Yani I, Septano GD. Characteristics of a PVDF–Tin Dioxide Membrane Assisted by Electric Field Treatment. Membranes (Basel). 2022;12(8):772. DOI: 10.3390/membranes12080772
- 52. Roni MdNP, Neshath TA, Hakim MdA, Hasan MdM, Rahman MH, Hossan MdS, et al. Optimizing β-Phase Content in PVDF Membranes via Modification of Dope Solution with Citric Acid/Nano-TiO2 Using Nonsolvent-Induced Phase Separation Method. Polymers (Basel). 2025;17(4):481. DOI: 10.3390/polym17040481
- 53. Mokarizadeh H, Raisi A. Industrial wastewater treatment using PES UF membranes containing hydrophilic additives: Experimental and modeling of fouling mechanism. Environ Technol Innov. 2021;23:101701. DOI: 10.1016/j.eti.2021.101701
- 54. Wang B, Fang L, Bao W, Fang K. Synergistic regulation of phase separation and crystallization via PCL blending: A paradigm shift for high-performance PET/PCL composite hollow fiber membranes in vascular grafts. Polymer (Guildf). 2026;356:130081. DOI: 10.1016/j.polymer.2026.130081
- 55. Shakeri N, Barzegar B, Habibi R, Aghdasinia H, Altinkaya SA. Enhanced performance and anti-fouling properties of polyether sulfone (PES) membranes modified with pistachio shell-derived activated carbon (PSAC)@ZIF-8&ZIF-67 to remove dye contaminants. Int J Biol Macromol. 2024;283:137654. DOI: 10.1016/j.ijbiomac.2024.137654
- 56. Alkandari SH, Castro-Dominguez B. Electro-casting for Superior Gas Separation Membrane Performance and Manufacturing. ACS Appl Mater Interfaces. 2023;15(48):56600–11. DOI: 10.1021/acsami.3c14742
- 57. Tayyab KM, Aadil M, Park CH. Ongoing phase separation inside hollow fiber membranes via non-solvent induced phase separation. Journal of Membrane Science Letters. 2025;5(2):100106. DOI: 10.1016/j.memlet.2025.100106
- 58. Sun H-L, Wang L-C, Zhou X-Y, Wei Y-M, Liu M. A dual VIPS-RTIPS phase inversion technique for fabricating high-performance polyethersulfone (PES) ultrafiltration membranes. Chem Eng Sci. 2026;321:122821. DOI: 10.1016/j.ces.2025.122821
- 59. Ibrahim Y, Khatri M, Khanzada NK, Hilal N. Electrically conductive membranes featuring integrated porous feed spacers for superior antifouling performance. NPJ Clean Water. 2025;8(1):64. DOI: 10.1038/s41545-025-00497-9
- 60. Alayande AB, Goh K, Son M, Kim C-M, Chae K-J, Kang Y, et al. Recent Progress in One- and Two-Dimensional Nanomaterial-Based Electro-Responsive Membranes: Versatile and Smart Applications from Fouling Mitigation to Tuning Mass Transport. Membranes (Basel). 2020;11(1):5. DOI: 10.3390/membranes11010005
- 61. Arahman N, Rosnelly CM, Aulia MP, Haikal RD, Yusni, Ambarita AC, et al. Exploring the effect of CNTs and pluronic on characteristics and stability of polyethersulfone (PES) and polyvinylidene fluoride (PVDF) membranes. Case Studies in Chemical and Environmental Engineering. 2024;10:100777. DOI: 10.1016/j.cscee.2024.100777
- 62. Fuseini M, El‐Shazly AH, Zaghloul MMY. Recent Progress in Membrane Engineering: Advanced Materials and Manufacturing Techniques. Polym Adv Technol. 2025;36(12). DOI: 10.1002/pat.70468
- 63. Allaf RM, Futian M. Solid-state blending for the preparation of porous eco-friendly PCL membranes: Potential for filtration applications. Journal of Plastic Film & Sheeting. 2023;39(4):375–98. DOI: 10.1177/87560879231186427
- 64. Ghadhban MY, Rashid KT, A. AbdulRazak A, Alsalhy QF. Recent progress and future directions of membranes green polymers for oily wastewater treatment. Water Science and Technology. 2023;87(1):57–82. DOI: 10.2166/wst.2022.409
- 65. Pervez MdN, Talukder ME, Mishu MR, Buonerba A, Del Gaudio P, Stylios GK, et al. One-Step Fabrication of Novel Polyethersulfone-Based Composite Electrospun Nanofiber Membranes for Food Industry Wastewater Treatment. Membranes (Basel). 2022;12(4):413. DOI: 10.3390/membranes12040413
- 66. Cheng X, Bae J. Recent Advancements in Fabrication, Separation, and Purification of Hierarchically Porous Polymer Membranes and Their Applications in Next-Generation Electrochemical Energy Storage Devices. Polymers (Basel). 2024;16(23):3269. DOI: 10.3390/polym16233269
- 67. Eniola JO, Kujawa J, Nwokoye A, Al-Gharabli S, Avornyo AK, Giwa A, et al. Advances in electrochemical membranes for water treatment: A comprehensive review. Desalination Water Treat. 2024;319:100450. DOI: 10.1016/j.dwt.2024.100450
- 68. Geleta TA, Maggay IV, Chang Y, Venault A. Recent Advances on the Fabrication of Antifouling Phase-Inversion Membranes by Physical Blending Modification Method. Membranes (Basel). 2023;13(1):58. DOI: 10.3390/membranes13010058
- 69. Arahman N, Rosnelly CM, Aulia MP, Haikal RD, Yusni, Ambarita AC, et al. Exploring the effect of CNTs and pluronic on characteristics and stability of polyethersulfone (PES) and polyvinylidene fluoride (PVDF) membranes. Case Studies in Chemical and Environmental Engineering. 2024;10:100777. DOI: 10.1016/j.cscee.2024.100777
- 70. Kiamehr Z, Shafiee M, Shokri B. Improving physico-chemical properties and antifouling of nanofiltration membranes using coating DLC nanostructures.
- 71. Huang S, Ras RHA, Tian X. Antifouling membranes for oily wastewater treatment: interplay between wetting and membrane fouling.
- 72. Sun F, Yang J, Shen Q, Li M, Du H, Xing DY. Conductive polyethersulfone membrane facilely prepared by simultaneous phase inversion method for enhanced anti-fouling and separation under low driven-pressure. J Environ Manage. 2021;297:113363. DOI: 10.1016/j.jenvman.2021.113363
- 73. Wen X, He C, Hai Y, Ma R, Sun J, Yang X, et al. Fabrication of an antifouling PES ultrafiltration membrane via blending SPSF. RSC Adv. 2022;12(3):1460–70. DOI: 10.1039/D1RA06354E
- 74. Russo F, Bulzomì M, Di Nicolò E, Ursino C, Figoli A. Enhanced Anti-Fouling Behavior and Performance of PES Membrane by UV Treatment. Processes. 2021;9(2):246. DOI: 10.3390/pr9020246
- 75. Ibrahim Y, Hilal N. Integration of Porous and Permeable Poly(ether sulfone) Feed Spacer onto Membrane Surfaces via Direct 3D Printing. ACS Applied Engineering Materials. 2024;2(4):1094–109. DOI: 10.1021/acsaenm.4c00086
- 76. Luo T, Xiao X, Du J, Sheng K, Liu R, Yuan S, et al. Recent Advances in Polymeric, Inorganic, and Mixed Matrix Membranes for Pervaporation Desalination. Environmental Chemistry and Safety. 2025;1(1):9600006. DOI: 10.26599/ECS.2025.9600006
- 77. Zhang Z, Zhang Y, Guo Y, Qian C, Chen K, Fang S, et al. Preparing gelatin-containing polycaprolactone / polylactic acid nanofibrous membranes for periodontal tissue regeneration using side-by-side electrospinning technology. J Biomater Appl. 2024;39(1):48–57. DOI: 10.1177/08853282241248778
- 78. Alsohaimi IH. Comparative study of PS and PES and their sulfonated forms in antifouling behavior and rejection efficiency. J King Saud Univ Sci. 2024;36(11):103576. DOI: 10.1016/j.jksus.2024.103576
- 79. Wang L, Liu J, Zhang R, Wu J, Tian X, Chen L, et al. Superhydrophilic fluorinated heterogeneous membranes with boosting antifouling property and high stable permeance for efficient emulsion separation. J Memb Sci. 2024;691:122253. DOI: 10.1016/j.memsci.2023.122253
- 80. The Organisation for Economic Co-operation and Development. OECD GUIDELINES FOR THE TESTING OF CHEMICALS [Internet]. 2025 [cited. Available from: http://www.oecd.org/termsandconditions/
- 81. Expert Meeting of Joint Research for Chemicals between China J and K. Comparison of fish acute toxicity tests using zebrafish reports from China, Japan and Korea-3,4-Dichloroaniline-Expert Meeting of Joint Research for Chemicals between. 2017.
- 82. The Organisation for Economic Co-operation and Development. OECD/OCDE 227 OECD GUIDELINE FOR THE TESTING OF CHEMICALS Terrestrial Plant Test: Vegetative Vigour Test. 2006.
- 83. The Organisation for Economic Co-operation and Development. OECD/OCDE 208 OECD GUIDELINES FOR THE TESTING OF CHEMICALS Terrestrial Plant Test: Seedling Emergence and Seedling Growth Test. 2006.