Articles
DOI DOI: 10.62441/actainnovations.vi.728

ANALYSIS OF THE CHARACTERISTICS AND PERFORMANCE OF POLYETHERSULFONE/POLYCAPROLACTONE MEMBRANES FABRICATED USING THE ELECTRIC FIELD METHOD FOR WATER FILTRATION APPLICATIONS

Abstract

This study developed polyethersulfone/polycaprolactone (PES/PCL) composite membranes using the electric field-assisted non-solvent induced phase separation (NIPS) method for water filtration applications. The effect of PES/PCL composition and electric field application on membrane morphology, hydrophilicity, mechanical properties, chemical stability, permeability, and filtration performance was systematically investigated. Four membrane samples were prepared, consisting of MM0 (100% PES, conventional NIPS), MM1 (70% PES + 30% PCL), MM2 (80% PES + 20% PCL), and MM3 (90% PES + 10% PCL), with the latter three fabricated under a 15 kV electric field. SEM and AFM analyses revealed that MM1 exhibited the most homogeneous interconnected finger-like pore structure, the largest pore size, and the smoothest surface morphology. FTIR and XRD analyses confirmed good intermolecular interactions between PES and PCL and improved semi-crystalline structure in MM1. Hydrophilicity tests showed that MM1 achieved the highest porosity (89.27%), water uptake (145.15%), and the lowest tortuosity (1.12). Mechanical testing demonstrated superior tensile strength (21.07 MPa) and structural stability for MM1. In addition, MM1 exhibited the highest clean water permeability of 114.3 L·m⁻²·h⁻¹·bar⁻¹ and the best rejection efficiency for electrical conductivity, total dissolved solids, and turbidity. Overall, the combination of PES/PCL blending and electric field-assisted NIPS effectively enhanced membrane performance for advanced water filtration applications.

How to Cite

Mataram, A., Gantada, M. S. P., Dani, R., Ismail, A. F., Sriyanti, I., Nasution, J. D., … Yuliandi, R. B. (2026). ANALYSIS OF THE CHARACTERISTICS AND PERFORMANCE OF POLYETHERSULFONE/POLYCAPROLACTONE MEMBRANES FABRICATED USING THE ELECTRIC FIELD METHOD FOR WATER FILTRATION APPLICATIONS. ACTA INNOVATIONS, 61, 52–83. https://doi.org/10.62441/actainnovations.vi.728

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